Transparent materials based on semiconducting ZnO: glass-ceramics and optical ceramics doped with rare-earth and transition-metal ions

-doped chalcogenide glass-ceramics based on selenium

Rare earth doped glass-ceramics transparent in the infrared region up to 16 μm have been prepared and studied. The enhancement of the emission of Er 3+ ions at 1.54 μm with increasing crystallinity was demonstrated in a seleniumbased glass-ceramic having a composition of 80GeSe2-20Ga2Se3+1000 ppm Er. The optical transmission, microstructure and luminescence properties of a base glass and glass-...

The Crystallization Effect on the Optical Properties of Oxyfluoride Glass-Ceramics Containing CaF2 Nanocrystals Doped with Y3+ Ions

In the present study, the oxyfluoride glasses of SiO2-Al2O3-CaF2 system containing different amounts of Y3+ ions were prepared through the convenient melting method. The crystallization temperatures and size of the CaF2 nanocrystals were obtained from DTA curves and XRD patterns, respectively. As a consequence, the optimum amount...

Metal Oxide ZnO-Based Varistor Ceramics

Tm3+ Modified Optical Temperature Behavior of Transparent Er3+-Doped Hexagonal NaGdF4 Glass Ceramics

Er3+-doped and Er3+-Tm3+-co-doped transparent hexagonal NaGdF4 glass ceramics are fabricated via melt-quenching method. The emissions of Er3+-doped NaGdF4 glass ceramics are adjusted from the green to red by varying the concentration of Tm3+ ion under the excitation of 980 nm. The spectrum, thermal quenching ratio, fluorescence intensity ratios, and optical temperature sensitivity of the transp...

Microstructure of Transparent Strontium Fresnoite Glass-Ceramics

Glass-ceramics grown from a glass of the composition Sr2TiSi2.45O8.9 (STS 45) are analyzed by scanning electron microscopy (SEM) and electron backscatter diffraction (EBSD). Oriented nucleation with the c-axes preferably perpendicular to the surface is detected. A very strong 001-texture is observed after only 10 μm of growth into the bulk, making this the first system in which an orientation p...